Combining Spintronics and Quantum Thermodynamics to Harvest Energy at Room Temperature

October 04, 2019 by Paul Shepard

An international scientific team from the CNRS, the University of Strasbourg and University of Lorraine in France, together with the Uppsala University in Sweden, has discovered a new thermal energy harvesting concept at the poorly understood/documented intersection between two otherwise disjointed research fields.

Illustrated above is a spin-polarized energy landscape describing the spin engine, leading to a spontaneous bias voltage at room temperature (credit: Martin Bowen). The paper, "Spin-driven electrical power generation at room temperature," was published in the journal Nature.

Spintronics comprises next-generation, low-power electronics that utilize the electron's quantum spin property. It is thus mostly concerned with information storage/communication technologies. Quantum physics/thermodynamics aims to reexamine the rules of thermodynamics when matter is confined at the nanoscale to exhibit quantum properties, and thus to understand how quantum engines operate.

The team's experiments and analyses show that it is possible to assemble an electrical generator that utilizes the electron spin to harvest thermal fluctuations at room temperature. Referring to the engine's schematic, the harvesting of ambient temperature occurs over paramagnetic (PM) centers —- atom-level magnets whose orientation fluctuates due to heat. The engine's electrodes, called spintronic selectors, allow electrons of only one spin (↑ in red, or ↓ in blue) to conduct.

Because heat mixes the electron spin on the PM center (middle) with energetically separated spin energy levels, transport (yellow lines) between the PM center and the electrodes occurs at different energy levels for each electrode. This causes a spontaneous bias voltage V to appear between the electrodes, and thus a spontaneous current to flow once the electrical circuit is closed.

The team utilized analytical and ab-initio theories to establish a link between this spin engine concept and room-temperature experiments on a solid-state spintronic device called a magnetic tunnel junction (MTJ). Here, the interface between the ferromagnetic metal Co and carbon atoms was used as a spintronic selector, and carbon atoms substituting oxygen atoms in the MgO tunnel barrier as PM centers.

According to the experiments, if such devices could be mass produced at high success yields, then at present densities of MgO MTJs within next-generation memories, this concept could yield chips that continuously produce electrical power with an areal power density that is 3x greater than raw solar irradiation on Earth.

The challenge is now to confirm certain fundamental aspects of this engine's operation, to achieve device reproducibility by controlling at the atomic level the position and properties of the PM centers in a suitable solid-state device, to implement CMOS back-end integration (e.g. thanks to existing progress with MgO MTJ technologies), to manage engineering issues such as heat flow and interconnect losses, and to drastically lower the resulting chip's areal cost.